Copper-catalyzed silylation of cyclopropenes using (trifluoromethyl)trimethylsilane.
نویسندگان
چکیده
A variety of cyclopropenes undergo direct silylation using (trifluoromethyl)trimethylsilane in the presence of a copper-bisphosphine catalyst; under these conditions, cyclopropenes that might otherwise undergo ring-opening are silylated efficiently.
منابع مشابه
A synthesis of γ-trifluoromethyl α,β-unsaturated γ-butyrolactones using CF(3)SiMe(3) as a trifluoromethylating agent.
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عنوان ژورنال:
- Chemical communications
دوره 9 شماره
صفحات -
تاریخ انتشار 2008